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URETHANE ELASTOMERS 101

(What are they and where they are used)


 

WHAT ARE CASTABLE URETHANE ELASTOMERS?

Castable Urethane ELASTOMERS are materials which can be stretched and will recover instantaneously on release. They are thermosetting, as are natural and synthetic rubbers. In simple terms, an Elastomer is a material which can be stretched at room temperature to twice its own length, held for five minutes, and upon release, will return to within 10% of its original length over a period of time. Once cured these materials are not re-formable and can not be liquefied by the application of heat, like thermoplastics.   

THE MAIN SIGNIFICANT PROPERTIES OF CASTABLE ELASTOMERS

There are basically two types of Castable Urethane Elastomers. They are based on either POLYETHERS and/or POLYESTERS. Both Polyether and Polyester based elastomers have excellent physical properties, including abrasion resistance, load bearing characteristics and many other useful properties like tensile strength and tear resistance. These are tough durable materials that offer unique advantages over other materials. The cured properties of these products bridge the gap between rubber, plastics and and those available using metals. The properties include outstanding abrasion, tear and flex resistance, good tensile strength and excellent impact resistance. These products excel in application where severe wear is a problem and will withstand pounding, abrasion, cutting and general abuse only to come back for more. Indeed, there are many applications where the parts will never wear out. 

Since these Urethanes are processed in liquid form, the required moulding pressures are low, therefore the tooling does not have to be extremely strong, heavy or expensive. Moulds can be manufactured from variety of materials like steel, aluminum, wood, urethane or epoxy. With proper techniques, moulds can be made using an original part as the model. There is virtually no limit to the size of the part that can be cast. As with other forms of Urethanes, the Castable liquids are supplied as both Polyether and Polyester based systems. Polyester Urethanes are excellent for printing applications where organic solvents are present. They are excellent in both dry and moist environments.    

 

PHYSICAL PROPERTIES

One of the important advantages of Cast Urethanes is the extremely wide hardness range within which parts can be moulded. The typical range is from a low hardness of  5-10 Shore “A” which is softer than gum eraser to about 85 on the “D” scale which is perhaps harder than a bowling ball.

The next most visible property is probably the wide range of available resilience (bounce). Urethanes can be formulated to a low of 10% rebound (Bayshore) to a very lively 65%. The most important characteristics are physical strength, resistance to abrasion and tear resistance.

 

ABRASION RESISTANCE:                       

Urethane Elastomers offer outstanding durability when compared with rubber, plastics or even metal. In many applications the unusual combination of properties has made it possible to design and fabricate products from Urethane Elastomers using less material than has been possible with other elastomers.

TYPICAL APPLICATIONS REQUIRING ABRASION RESISTANCE:

Chute Liners

Cyclone and Cyclone Liners

Conveying System Liners

Duct Liners

Pump Seals

Rod Wipers

Snow Plough Blades

Pinch Valves

Pulley and Sheave Liners

Caster Wheels

Industrial Tires

Agitator Blades

Pump Liners

Hopper Liners

Pallet Wheels

Roller Skate Wheels

 

COMPRESSIVE PROPERTIES:

Cast Urethanes have greater load bearing capability than do conventional elastomers of equal hardness. As the hardness is increased, properties such as tensile strength, tear strength, compressive strength and tensile modulus are also increased.

High load-bearing capacity plus the unusual combination of hardness, resilience, solvent and oil resistance, in addition to abrasion resistance have been decisive factors in specifying these products for rolls and rollers.

TYPICAL APPLICATIONS REQUIRING COMPRESSIVE STRENGTH:

 Graphic Art Rollers

Fork Lift truck Wheels

Conveyer Wheels

Business Machine Rolls

Squeeze Rolls

Coating Rolls

Forming Rolls Feed Rolls

Gaskets and Seals

Nip Rolls

Rolls for Steel and Aluminum mills

Transport Rollers

Heavy Duty conveyer rolls

Pulleys

 

 

MECHANICAL PROPERTIES:

Great toughness combined with the many other outstanding properties associated with the high hardness Urethanes, leads to many unusual applications. Easily fabricated and machined gears are now being made from Castable Elastomers. Not only are they less costly to produce, they also provide smooth, quiet operation with minimum of wear and absolutely no corrosion problems.

TYPICAL APPLICATIONS REQUIRING MECHANICAL STRENGTH:

Bumpers

Shock Absorbers

Bushings

Bearings

Wear Strips, Slide Plates

Machine Parts

Housings

Escalator parts

Car Wash rollers

Couplings

Fixture Blocks

Grommets

Hammers

Striker Pads

Wood-sorter pads

Gears and Sprockets

Balls for Pump Check Valves

 

ELECTRICAL PROPERTIES:

Cast Urethanes have very good insulating properties and are used in many potting and encapsulating applications.

MOISTURE RESISTANCE:

Urethanes are very resistant to the swelling and deterioration caused by moisture and have excellent long term stability in water up to 120ºF. Due to their nature however continuous use in hot water over 185ºF is not recommended.

Moisture absorption is normally very low, in the range of .3 to 2% by weight and the increase in volume (swell) is negligible. For example, Castable Urethanes can operate at close tolerance in Water lubricated bearings without fear of seizure.

TYPICAL APPLICATIONS REQUIRING MOISTURE RESISTANCE:

Suction Rolls in Pulp and Paper mills            Pump Liners             Pump Impellers


MOULD MILDEW AND FUNGUS RESISTANCE:

Polyether Polyurethanes do not support fungus growth and are highly resistant to such attack.

IN SUMMATION:   

Polyurethane elastomers are most suited to applications where durability, flexibility, elasticity and abrasion resistance are prime requirements. They are less exothermic (heat generating) during the reaction than other types of materials and as a result suited to large mass castings. 

Acknowledgement:

We are thankful to the “CANADIAN URETHANE MANUFACTURING ASSOCIATION” for the valuable information provided to us for this article. 

 

 

          

 


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Last modified: June 20, 2007